The draw is to be screened live on BT Sport 3 and BBC 2, with the show starting at 7pm and the actual draw scheduled to start from approximately 7.10pm.
The Hatters and their fellow League Two and One clubs join the Non-League clubs who progressed through this weekend's fourth qualifying round, with first round ties scheduled to take place on the weekend of November 3-6.
Winning teams at that stage bank £18,000 from the FA’s prize fund.
Make sure you tune in to see who the Hatters get as they embark on the road to Wembley!
For all the ball numbers, click here